P,N-Chelated Gold(III) Complexes: Structure and Reactivity
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چکیده
منابع مشابه
Reactivity and derivatization of five-coordinate, chelated aluminum.
The convenient five-coordinate starting materials, Salen((t)Bu)AlCl (Salen((t)Bu) = N,N'-alkylene (or arylene) bis (3,5-di-tert-butyl-2-hydroxybenzylideneamine) (1-4) can be used in a wide range of reactions to form five-coordinate aluminum compounds. Herein, these reagents were used to produce new five-coordinate azides, LAlN(3) (L = Salen((t)Bu) (5), Salpen((t)Bu) (6), and Salomphen((t)Bu) (7...
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The rate of displacement of the aqua ligands by three neutral nucleophiles (Nu) of different steric demands, namely thiourea (tu), N,N'-dimethylthiourea (dmtu) and N,N,N',N'-tetramethylthiourea (tmtu) and an anionic nucleophile (I(-)) in complexes of the form [{Pt(H(2)O)}(2)(N,N,N',N'-tetrakis(2-pyridylmethyl)-N(CH(2))(n)N](CF(3)SO(3))(4), n = 2 (En); 3 (Prop); 4 (But); 6 (Hex); 8 (Oct) and 10 ...
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ژورنال
عنوان ژورنال: Inorganic Chemistry
سال: 2020
ISSN: 0020-1669,1520-510X
DOI: 10.1021/acs.inorgchem.0c02720